Ionic Liquid

What is an Ionic Liquid?

A salt (a compound consisting of a cation and an anion) that has a low melting point and is a liquid near room temperature.

Comparison of Appearance of Inorganic Salts and Ionic Liquids

Main Features of Ionic Liquids

1

Low Melting Point

Ionic compounds generally have a high melting point, while ionic liquids have a low melting point due to their structure that weakens interactions and inhibits crystallinity.
(The melting point can be controlled by molecular design and combination of anions and cations.) 

Lower electron density of ionic groups due to electron-withdrawing groups, etc., results in a lower melting point 

2

Low Volatility 

The vapor pressure is very low due to the presence of electrical interactions between ions.  There is little concern about air pollution or ignition due to volatilization. 

Difference between organic solvents and ionic liquids 
Organic solventIonic liquid
Volatile
Air pollution and ignition concerns
Low volatility
Less concern about air pollution and ignition
Vapor pressure of each liquid

3

High Ionic Concentration and High Conductivity 

Since it is composed solely of ions, it has a high ionic concentration and high electrical conductivity. 

Electrical conductivity of each liquid

Examples of Industrial Applications of Ionic Liquids

Industrial Applications of Ionic Liquids Part 1:  Electrolyte for Capacitors 

Why Ionic Liquids are Used as Electrolyte for Capacitors? 

  • Low melting point: No precipitation even at low temperatures 
  • High conductivity: High conductivity can be achieved by increasing the concentration of electrolyte

Conductivity and Low Temperature Solubility Data for Ionic Liquids and General Amine Salts 

Our electrolyte
 (Ionic liquid)
Triethylamine phthalate
 (Non-ionic liquid)
Conductivity mS/cm​(@30℃) 14.2​ 6.0​
Low temperature solubility( -55℃)​ Good (Dissolution)  Poor (precipitation) 

High Conductivity by Ionic Liquids

Antistatic Agent - Fluorine-free ionic liquid  product developed by our company 

Our developed product uses a composition that does not contain fluorine elements and has low corrosiveness.  
In addition, its large molecular size makes it difficult to bleed out.  

Industrial Applications of Ionic Liquids Part 2: CO2 Gas Absorbent 

Why Ionic Liquids are Used

  • Low volatility: Low loss in process
  • Design freedom: Can be selectively structured to easily adsorb CO2 

     (1)Adsorption in crevices due to its bulky structure (physical adsorption) 

     (2)Reacts with CO2(chemisorption)


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