Stretchable UV Curing Resin"STRTECH"(Developed products)

Stretchable UV-curable resin for electronics with excellent resilience properties

What is Great about Sanyo Chemical's Stretchable UV-curable Resin ”STRTECH“ 

1

UV curable resin with high elasticity and resilience properties

Traditionally, because UV-curable resins are often brittle and hard, thermosetting and thermoplastic elastic materials such as silicone and urethane resins have been mainly used for such flexible wearable devices. However, it is usually difficult to achieve both elasticity and resilience (the property of returning to the original shape after deformation), and when conventional elastic materials are tried to be elastic enough to follow the movement of skin and joints, there is a delay in restoration or the material does not return to its original shape after repeated use.

“STRTECH” is a new material that is a UV curable resin, yet it is soft, flexible, and freely stretchable, and has high resilience properties that allow it to return to its original shape even after repeated expansion and contraction. Since it can follow complex movements, it is expected to be applied to flexible wearable devices that can follow the body's movements and be worn on the skin without discomfort.

UV curable resin with high resilience properties

Resilience: 99% or more restored even after 50% elongation

2

High adhesion to metal, glass, etc.

“STRTECH” has excellent adhesion to metals such as copper and silver, and is expected to be used for encapsulants for circuit boards and sensors, as well as for film substrates*. 
*Flexible wearable devices use flexible  and stretchable thin film as a substrate for circuits and other devices. 

3

Adaptable to various printing methods such as IJ and screen printing

“STRTECH” can be customized in viscosity and other properties ranging from liquid to film, and is applicable to various processes such as coating and printed wiring formation.

In addition, since it is UV curable, it can be cured in a shorter time than thermosetting, and heating, drying, and other processes are not required, making it possible to shorten the production process. In addition, since no heating is required, it is useful for reducing CO2 emissions, thus contributing to carbon neutrality. In addition, the use of thermosensitive materials and heat-sensitive organic materials can be used without requiring high heat for curing, thereby expanding the range of material choices. 

Comparison
STRTECH TPU Silicone
Processability Excellent Poor Poor
Flexibility Good Fair Good
Heat resistance Good Poor Good
Adhesion Good Good Poor

Application Example of “STRTECH” to Stretchable Sensors
(Joint research with Tokito Laboratory, Yamagata University)

Through joint research with a research group led by Professor Tokito of Yamagata University (Organic Electronics Research Center), a leading researcher in flexible printed electronics, we have confirmed the effect of restorative properties when “STRTECH” film is used for strain sensors. Furthermore, using “STRTECH” as an encapsulant for sensors, we have also confirmed that the resistance waveform does not change before and after encapsulation. 

Study of application to sensor substrate materials

Figure1:Resistance vs. Bending time

Higher response to deformation than conventional products

Test method: The conductivity-sensitive layer* printed on the film substrate is subjected to expansion and contraction, resulting in a change in resistivity, and the degree of strain is detected.

※Made of carbon black (CB) and polydimethylsiloxane (PDMS)

Test conditions: The sensor was pulled at a strain range of 50% and a tensile speed of 0.2 mm/sec, and the change in resistance over time was measured.

Study of application to sensor encapsulation materials

Figure2:Resistance vs. Bending time

No change in sensor characteristics when subjected to strain

Test conditions: The sensor was pulled at a strain range of 50% and a tensile speed of 0.2 mm/sec, and the change in resistance over time was measured.

■ FHE substrate encapsulation study

・Protects wiring and chips by following the deformation of the board.
・Does not affect sensor characteristics even after encapsulation.


Fig. Cross-sectional view of FHE-type strain sensor and actual

Physical Properties of “STRTECH” Products

Typical values are listed.
Grade STRTECH
ST-101
STRTECH
ST-201NA
STRTECH
ST-202NA
Liquid Viscosity [mPa・s] 22 1,900 12,000
After curation Optical Transmission [%] >95 No data No data
Physical properties Elastic modulus [MPa] 62 < 10 < 10
Elongation at break [%] 180 400 480
Recovery rate [%] >99 >99 >99
Heat resistance Dimensional change rate [%]
150℃, 1h
No data < 1 < 1
Other Adhesion on metal 100/100 No data No data
Measurement condition

-Viscosity: Type E viscometer (25°C)

-Transmittance: film thickness of approx. 10 μm, measured with a haze meter

-Modulus of elasticity and elongation at break: Samples were prepared in strips (40 mm x 15 mm x 0.1 mmt) and measured at a distance of 20 mm between chucks and at a tensile speed of 10 mm/min.

-Recovery rate: Measure the dimensional change before and after the test after the cured material with a film thickness of approximately 200 μm is elongated by 50% and recovered.

-Dimensional change rate: Dimensional change before and after heating is measured with an optical microscope.

-Metal adhesion: Measured with 100 mask loss cut on a copper plate coated with approx. 10 μm-thick resin.
(Curing conditions: D bulb 4000 mJ (1000 mW/cm2), under nitrogen atmosphere)

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