We were the first company in Japan to succeed in the industrialization of synthetic waxes. We manufacture and sell low molecular weight polypropylene ("VISCOL") and low molecular weight polyethylene ("SANWAX").
"VISCOL" and "SANWAX" have a wide molecular weight distribution unique to thermal decomposed polyolefin waxes and exhibit the following characteristics.
Pigment Dispersants
Processability Improver for Plastics
Manufacturing method | Thermally decomposed polyolefin wax (our product) | Polymerization type (high pressure) |
Polymerization type (low pressure) |
---|---|---|---|
Molecular weight distribution Mw/Mn |
wide |
narrow | narrow |
Spatial structure | Contains long-chain branching | Contains short-chain branching (usually methyl group) |
Contains long-chain branching |
VISCOL 330‐P |
VISCOL 440-P |
VISCOL 550-P |
VISCOL 660-P |
VISCOL |
VISCOL LM-600 (Development product) |
|
---|---|---|---|---|---|---|
Features | High molecular weight | Medium to high molecular weight | low molecular weight | low molecular weight | High molecular weight Low melting point |
Low molecular weight Low melting point |
Appearance | White powder | White powder | White powder | White powder | Light yellow powder | Light yellow powder |
APHA color scale | 200 | 200 | 200 | 1 | 1 | 1 |
Melting point (°C) | 145 | 144 | 139 | 136 | 125 | 119 |
Melt viscosity (mPa-s) | 4000 | 1800 | 200 | 70 | 1400 | 100 |
Molecular weight (Mw) | 40000 | 27000 | 13000 | 10000 | 30000 | 9000 |
Main applications | Pigment dispersants, filler dispersants, melt-flow improvers |
Color number: Hazen method (*Gardner method), Melting point: DSC method, Melt viscosity: 160°C (*140°C), Molecular weight: High temperature GPC method
SANWAX 161‐P |
SANWAX 131-P |
SANWAX 151-P |
SANWAX 171-P |
|
---|---|---|---|---|
Features | High molecular weight | Medium to high molecular weight | Low molecular weight | Low molecular weight |
Appearance | White powder | White powder | White powder | White powder |
APHAcolor scale | 30 | 30 | 30 | 30 |
Melting point (°C) | 103 | 102 | 101 | 100 |
Melt viscosity (mPa-s) |
4300 | 1000 | 290 | 180 |
Molecular weight (Mw) | 27000 | 20000 | 13000 | 10000 |
Main applications | Pigment dispersants, filler dispersants, melt-flow improvers |
Color number: Hazen method, Melting point: DSC method, Melt viscosity: 140°C, Molecular weight: High temperature GPC method
Dispersion (mainly pigments) | Mold release | Viscosity adjustment | Lubrication | |
---|---|---|---|---|
Target resins Common SANWAX VISCOL |
PE PP |
EPDM | PE PP |
ABS PBT PVC PPS PC PS |
Mechanism |
Polyolefin waxes penetrate between pigments and resins to create dispersion. |
Mold-releasing properties develop due to easy migration of polyolefin wax to the surface. | Adding low molecular weight materials improves flowability during molding. | Polyolefin waxes are less compatible with the above resins and tend to migrate to the surface, thus acting as an external lubricant. |
Addition of polyolefin wax reduces resistance (torque) when PVC and stearate are melt-blended.
PVC : 100wt%, Stearic acid Calcium stearate: 2.5wt%, Zinc stearate: 1.0wt% , Dioctyl tin Malate polymer: 0.5wt%, Lubricant: 0.3-1.0wt Melt-kneaded using a lab-plast mill (temperature of mixer: 180°C) Mixer temperature: 180, 190, 200°C (mixer temperature: 180, 190, 200°C, screw speed: 50 rpm).
Polybutylene terephthalate (PBT) resin pre-dried at 130°C for 3 hours and "SANWAX 161-P" (0.5 wt%) were mixed in a twin-screw extruder (250°C) and injection molded (molding temperature: 250°C, mold temperature: 50°C) to produce test specimens.
Shear viscosity: Capillary rheometer method (240°C, 608/sec) Tensile test: ASTM D638, Flexural test: ASTM D790.
Without VISCOL | VISCOL developmental product (1wt% added) | VISCOL developmental product (2wt% added) | |
---|---|---|---|
Spiral flow length (mm) | 1250 | 1390 | 1430 |
Surface smoothness (Ra value)(μm) The smaller the Ra value, the smoother the surface. | 7.1 | 5.0 | 4.8 |
Tensile strength (MPa) | 118 | 116 | 112 |
Bending strength (MPa) | 171 | 168 | 167 |
Long glass fiber/PP resin pellets (glass fiber content: 30 wt%) were dry-blended with "VISCOL" and injection molded (molding temperature: 250°C, mold temperature: 50°C) to prepare test specimens for tensile and flexural tests.
Spiral flow length: Long glass fiber/PP resin pellets (glass fiber content: 30 wt%) were dry-blended with "VISCOL", injected into a spiral flow mold (Archimedes spiral), and the flow length was measured. (molding temperature: 230°C, mold temperature: 50°C, injection pressure: 30 kgf/cm2, mold flow channel width: 6 mm, channel thickness: 3 mm), Surface smoothness: Ra value was measured using a laser microscope. Tensile test: ASTM D638, Bend test: ASTM D790.
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